1. Pablo Picasso: Picasso, one of the most famous painters of the 20th century, also experimented with ceramics. His approach to ceramics was highly experimental and improvisational, allowing him to create new forms and textures that he could not achieve with paint. This experimentation with ceramics had a significant impact on his approach to art-making, as he began to see his painting in a more sculptural way, using texture and form in new and innovative ways.

2. Claes Oldenburg: Oldenburg, an American sculptor known for his large-scale public installations, began using ceramics in the 1970s. His approach to ceramics was highly conceptual, as he used the medium to explore ideas of mass production and consumer culture. This experimentation with ceramics allowed him to create highly detailed and textured works that could not be achieved through other mediums, such as his ceramic hamburgers and ice cream cones.

3. Joan Miró: Miró, a Spanish painter and sculptor associated with the Surrealist movement, also experimented with ceramics. His approach to ceramics was highly experimental, as he explored new forms and textures that he could not achieve through painting or sculpture. This experimentation had a significant impact on his approach to art-making, as he began to see his painting and sculpture as more fluid and organic.

4. Lucio Fontana: Fontana, an Italian painter and sculptor associated with the Spatialist movement, also worked with ceramics. His approach to ceramics was highly experimental, as he used the medium to explore the relationship between art and space. This experimentation with ceramics had a significant impact on his approach to art-making, as he began to see his painting and sculpture as more three-dimensional, using ceramics to create new spatial dimensions.

5. Ruth Duckworth: Duckworth, a British-born American sculptor, primarily worked with ceramics throughout her career. However, her approach to ceramics was highly innovative, as she used the medium to create abstract and sculptural forms that were not typical of traditional ceramics. Her experimentation with ceramics allowed her to push the boundaries of the medium, creating highly abstract works that had a significant impact on the field of ceramics and sculpture as a whole.